Transmetalation is a key step in traditional coupling reactions. Herein we discuss the most recent progress in the metal–metal relay catalysis based on a transmetalation strategy. An efficient synthetic strategy for the formation of polysubstituted furan derivatives from cyclopropenes based on the tandem metal relay catalysis (TMRC reaction) is summarized.
C. Song, J. Wang and Z. Xu, Org. Biomol. Chem., 2014, 12, 5802 DOI: 10.1039/C4OB00987H
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