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Issue 29, 2014
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Electrophilic sulfhydration of 8-nitro-cGMP involves sulfane sulfur

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Abstract

The formation of 8-SH-cGMP from the reaction between hydrogen sulfide and 8-nitro-guanosine-3′,5′-cyclic monophosphate in the presence of thiols does not take place by nucleophilic attack of the hydrosulfide anion, as previously proposed, but first involves the formation of reactive species containing sulfane sulfur, like persulfides.

Graphical abstract: Electrophilic sulfhydration of 8-nitro-cGMP involves sulfane sulfur

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Publication details

The article was received on 28 Apr 2014, accepted on 11 Jun 2014 and first published on 12 Jun 2014


Article type: Communication
DOI: 10.1039/C4OB00868E
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Citation: Org. Biomol. Chem., 2014,12, 5360-5364
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    Electrophilic sulfhydration of 8-nitro-cGMP involves sulfane sulfur

    V. Terzić, D. Padovani, V. Balland, I. Artaud and E. Galardon, Org. Biomol. Chem., 2014, 12, 5360
    DOI: 10.1039/C4OB00868E

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