Jump to main content
Jump to site search

Issue 11, 2014
Previous Article Next Article

Dissecting non-covalent interactions in oxazaborolidinium catalyzed cycloadditions of maleimides

Author affiliations

Abstract

Substrate association and asymmetric induction in oxazaborolidinium-catalyzed cycloadditions of maleimides are shown to depend strongly on the catalyst's aromatic substituents. Favourable dispersive forces bias complexation to the catalyst's convex (exo) face exposing a single diastereoface of the substrate preferentially.

Graphical abstract: Dissecting non-covalent interactions in oxazaborolidinium catalyzed cycloadditions of maleimides

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 02 Jan 2014, accepted on 23 Jan 2014 and first published on 11 Feb 2014


Article type: Communication
DOI: 10.1039/C4OB00009A
Citation: Org. Biomol. Chem., 2014,12, 1717-1720
  •   Request permissions

    Dissecting non-covalent interactions in oxazaborolidinium catalyzed cycloadditions of maleimides

    R. S. Paton, Org. Biomol. Chem., 2014, 12, 1717
    DOI: 10.1039/C4OB00009A

Search articles by author