Issue 1, 2014

A core–shell–satellite structured Fe3O4@MS–NH2@Pd nanocomposite: a magnetically recyclable multifunctional catalyst for one-pot multistep cascade reaction sequences

Abstract

A hierarchical core–shell–satellite structured composite system Fe3O4@MS–NH2@Pd, which was composed of Pd nanoparticles well-dispersed on an amino group functionalized mesoporous silica (MS–NH2) nanosphere, and superparamagnetic Fe3O4 nanoparticles scattered inside the silica sphere, was prepared by using a facile procedure. The composite combined the catalytic properties of amino groups and Pd nanoparticles with superparamagnetic properties of magnetite into a single platform. This integrated nanosystem acted as an efficient magnetically recyclable noble metal-base multifunctional nanocatalyst and showed excellent catalytic activity, selectivity and stability for the direct synthesis of α-alkylated nitriles under mild conditions through facile one-pot multistep cascade reaction sequences.

Graphical abstract: A core–shell–satellite structured Fe3O4@MS–NH2@Pd nanocomposite: a magnetically recyclable multifunctional catalyst for one-pot multistep cascade reaction sequences

Supplementary files

Article information

Article type
Paper
Submitted
20 Aug 2013
Accepted
17 Oct 2013
First published
22 Oct 2013

Nanoscale, 2014,6, 442-448

A core–shell–satellite structured Fe3O4@MS–NH2@Pd nanocomposite: a magnetically recyclable multifunctional catalyst for one-pot multistep cascade reaction sequences

P. Li, Y. Yu, H. Liu, C. Cao and W. Song, Nanoscale, 2014, 6, 442 DOI: 10.1039/C3NR04427K

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