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Issue 4, 2014
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Strategies towards the synthesis of calyciphylline A-type Daphniphyllum alkaloids

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Abstract

Covering: up to September 2013

The Daphniphyllum alkaloids are a diverse family of natural products rich in number and structural diversity that have been known for many decades. However, the structurally unique subclass of calyciphylline A-type alkaloids has only recently been discovered and is relatively unexplored. Several noteworthy core syntheses and the development of a wide range of novel synthetic strategies have been achieved. This includes strategies based on intramolecular Michael addition, Pd-catalysis, cycloaddition, and Mannich-type reactions. This review will provide an overview of these synthetic studies.

Graphical abstract: Strategies towards the synthesis of calyciphylline A-type Daphniphyllum alkaloids

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Publication details

The article was received on 05 Nov 2013 and first published on 05 Mar 2014


Article type: Review Article
DOI: 10.1039/C3NP70115H
Citation: Nat. Prod. Rep., 2014,31, 550-562
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    Strategies towards the synthesis of calyciphylline A-type Daphniphyllum alkaloids

    B. Kang, P. Jakubec and D. J. Dixon, Nat. Prod. Rep., 2014, 31, 550
    DOI: 10.1039/C3NP70115H

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