Issue 10, 2014
From the journal:

New Journal of Chemistry

A hexanuclear manganese(ii) complex: synthesis, characterization and catalytic activity toward organic sulfide oxidation†

Mohammad Mahdi Najafpour,*ab   Mojtaba Amini,*c   Małgorzata Hołyńska,*d   Maryam Zaree  and  Emad Aminia  

* Corresponding authors

a Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran
E-mail: mmnajafpour@iasbs.ac.ir
Tel: +98 241 415 3201

b Center of Climate Change and Global Warming, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran

c Department of Chemistry, Faculty of Science, University of Maragheh, Golshahr, P.O. Box 55181-83111731, Maragheh, Iran
E-mail: mamini@maragheh.ac.ir
Tel: +98 421 2278900

d Fachbereich Chemie, Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany
E-mail: holynska@staff.uni.marburg.de
Tel: +49 6421282 25615

e Department of Basic Sciences, Golpayegan University of Technology, P.O. Box 8771765651, Golpayegan, Iran

Abstract

Herein we report on the synthesis and characterization of a hexanuclear [MnII6] wheel-like assembly with naphthalene-1,8-dicarboxylate and 1,10-phenanthroline as ligands. Overall antiferromagnetic behavior of the magnetic properties is observed. The complex acts as a catalyst toward organic sulfide oxidation in the presence of H2O2 with good selectivity (98–100%).

Graphical abstract: A hexanuclear manganese(ii) complex: synthesis, characterization and catalytic activity toward organic sulfide oxidation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4NJ01159G
Article type
Paper
Submitted
10 Jul 2014
Accepted
15 Aug 2014
First published
18 Aug 2014

New J. Chem., 2014,38, 5069-5074

Author version available

Download author version (PDF)

Permissions

Request permissions

A hexanuclear manganese(II) complex: synthesis, characterization and catalytic activity toward organic sulfide oxidation

M. M. Najafpour, M. Amini, M. Hołyńska, M. Zare and E. Amini, New J. Chem., 2014, 38, 5069 DOI: 10.1039/C4NJ01159G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements