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Issue 2, 2015
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Simple metal salts supported on montmorillonite as recyclable catalysts for intramolecular hydroalkoxylation of double bonds in conventional and VOC-exempt solvents

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Abstract

We describe herein an efficient and particularly sustainable catalytic system for the intramolecular hydroalkoxylation of double bonds. A heterogeneous catalyst based on the impregnation of benign metals such as iron and bismuth on montmorillonite was used for a highly atom-economic transformation in DMC, a non-VOC solvent. The transformation allowed the formation of a large range of cyclic ethers from the corresponding unsaturated alcohols and the catalyst could be recycled several times.

Graphical abstract: Simple metal salts supported on montmorillonite as recyclable catalysts for intramolecular hydroalkoxylation of double bonds in conventional and VOC-exempt solvents

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Publication details

The article was received on 13 Oct 2014, accepted on 04 Dec 2014 and first published on 05 Dec 2014


Article type: Communication
DOI: 10.1039/C4GC01990C
Author version available: Download Author version (PDF)
Citation: Green Chem., 2015,17, 837-841
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    Simple metal salts supported on montmorillonite as recyclable catalysts for intramolecular hydroalkoxylation of double bonds in conventional and VOC-exempt solvents

    I. Notar Francesco, B. Cacciuttolo, M. Pucheault and S. Antoniotti, Green Chem., 2015, 17, 837
    DOI: 10.1039/C4GC01990C

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