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Issue 3, 2016
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Unraveling the hidden function of a stabilizer in a precursor in improving hybrid perovskite film morphology for high efficiency solar cells

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Abstract

The morphology of the organometal trihalide perovskite (OTP) plays a critical role in the performance of solar cell devices. Nevertheless it has been frequently reported that the morphology of OTP films tends to be different in different laboratories even with the same film preparation procedure, which makes it very difficult to compare and understand the material and device physics. Here, we unravel a critical role of the H3PO2 stabilizer in HI, which has been largely ignored, in controlling the morphology of the perovskite films. The H3PO2 stabilizer in HI solution introduces MAH2PO2 impurities into the synthesized MAI (non-purified MAI) by reacting with methylamine (MA) aqueous solution. MAH2PO2 impurities can slow down the overall crystallization process of perovskite by forming an intermediate phase of Pb(H2PO2)2. Both MAH2PO2 and Pb(H2PO2)2 impede the fast reaction of PbI2 and MAI, resulting in highly uniform and smooth perovskite films with larger grain sizes. The recrystallization of non-purified MAI can remove the MAH2PO2 impurity and form purified MAI, which however results in rough and non-uniform perovskite films. Uniform and smooth perovskite films can also be obtained by directly adding artificially synthesized MAH2PO2 into the purified MAI precursor. This study also suggests Pb(H2PO2)2 to be a new precursor to form high quality perovskite films.

Graphical abstract: Unraveling the hidden function of a stabilizer in a precursor in improving hybrid perovskite film morphology for high efficiency solar cells

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Publication details

The article was received on 19 Jan 2016, accepted on 27 Jan 2016 and first published on 28 Jan 2016


Article type: Communication
DOI: 10.1039/C6EE00183A
Citation: Energy Environ. Sci., 2016,9, 867-872
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    Unraveling the hidden function of a stabilizer in a precursor in improving hybrid perovskite film morphology for high efficiency solar cells

    Z. Xiao, D. Wang, Q. Dong, Q. Wang, W. Wei, J. Dai, X. Zeng and J. Huang, Energy Environ. Sci., 2016, 9, 867
    DOI: 10.1039/C6EE00183A

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