Issue 4, 2015

The first example of a zirconium-oxide based metal–organic framework constructed from monocarboxylate ligands

Abstract

This work reports the first example of a Zr-based MOF which is exclusively constructed from the monocarboxylate ligand formate. Despite the low surface area, the new material exhibits an unexpectedly favourable affinity for carbon dioxide over nitrogen at room temperature.

Graphical abstract: The first example of a zirconium-oxide based metal–organic framework constructed from monocarboxylate ligands

Supplementary files

Article information

Article type
Communication
Submitted
16 Oct 2014
Accepted
20 Nov 2014
First published
20 Nov 2014

Dalton Trans., 2015,44, 1516-1519

Author version available

The first example of a zirconium-oxide based metal–organic framework constructed from monocarboxylate ligands

W. Liang, R. Babarao, M. J. Murphy and D. M. D'Alessandro, Dalton Trans., 2015, 44, 1516 DOI: 10.1039/C4DT03183K

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