Issue 48, 2014

Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

Abstract

4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.

Graphical abstract: Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2014
Accepted
17 Oct 2014
First published
17 Oct 2014

Dalton Trans., 2014,43, 17916-17919

Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

Ü. İşci, C. Caner, Y. Zorlu, A. G. Gürek, F. Dumoulin and V. Ahsen, Dalton Trans., 2014, 43, 17916 DOI: 10.1039/C4DT02412E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements