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Issue 42, 2014
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Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands

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Abstract

The geometry imposed by the coordination sphere around the metal, together with the choice of the “arms” can be advantageously used to build corannulene-based molecular tweezers, which show great affinities for C60 and C70, as revealed by NMR titration experiments, mass spectroscopy, DFT calculations and the single crystal X-ray structural analysis of the compound C601.

Graphical abstract: Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands

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Supplementary files

Publication details

The article was received on 09 Jul 2014, accepted on 16 Jul 2014 and first published on 06 Aug 2014


Article type: Communication
DOI: 10.1039/C4DT02078B
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2014,43, 15693-15696
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    Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands

    C. M. Álvarez, L. A. García-Escudero, R. García-Rodríguez, J. M. Martín-Álvarez, D. Miguel and V. M. Rayón, Dalton Trans., 2014, 43, 15693
    DOI: 10.1039/C4DT02078B

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