Issue 43, 2014
From the journal:

Dalton Transactions

Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment†

Ya Wang,a   Ning Jiang,a   Fengyan Li,*a   Yanzhen Zheng,b   Lin Xu*a  and  Minghui Suna  

* Corresponding authors

a Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
E-mail: linxu@nenu.edu.cn, lify525@nenu.edu.cn
Fax: +86-431-85099765
Tel: +86-431-85098760

b Center for Applied Chemical Research, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710054, P. R. China

Abstract

Two new cyanide-bridged heteropolymolybdate complexes have been synthesized by a facile self-assembly process in aqueous solution, which demonstrates a successful tactic to incorporate the cyanometalate fragment into lacunary heteropolymolybdate. Magnetic investigation showed that complex 2 exhibits slow magnetic relaxation behavior.

Graphical abstract: Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

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Article information

DOI
https://doi.org/10.1039/C4DT01875C
Article type
Communication
Submitted
23 Jun 2014
Accepted
30 Jul 2014
First published
31 Jul 2014

Dalton Trans., 2014,43, 16147-16151

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Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

Y. Wang, N. Jiang, F. Li, Y. Zheng, L. Xu and M. Sun, Dalton Trans., 2014, 43, 16147 DOI: 10.1039/C4DT01875C

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