Issue 41, 2014
From the journal:

Dalton Transactions

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes†

Madelyn Qin Yi Tay,a   Balasubramanian Murugesapandian,a   Yunpeng Lu,a   Rakesh Ganguly,a   Kinjo Reia  and  Dragoslav Vidović*a  

* Corresponding authors

a SPMS-CBC, Nanyang Technological University, 21 Nanyang Link, Singapore
E-mail: dvidovic@ntu.edu.sg
Fax: (+65) 6791 1961

Abstract

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

Graphical abstract: Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes

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Article information

DOI
https://doi.org/10.1039/C4DT01210K
Article type
Communication
Submitted
25 Apr 2014
Accepted
19 Aug 2014
First published
21 Aug 2014

Dalton Trans., 2014,43, 15313-15316

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Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes

M. Q. Y. Tay, B. Murugesapandian, Y. Lu, R. Ganguly, K. Rei and D. Vidović, Dalton Trans., 2014, 43, 15313 DOI: 10.1039/C4DT01210K

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