Issue 37, 2014
From the journal:

Dalton Transactions

Dinuclear Cu(ii) complexes based on two flexible Schiff-base ligands and one unusual in situ formed diphenolate 2,6-piperidin-4-one derivative†

Yuan Dai,a   Yin-Ge Wang,b   Jiao Geng,a   Yu-Xin Penga  and  Wei Huang*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
E-mail: whuang@nju.edu.cn

b College of Sciences, Nanjing Tech University, Nanjing, P. R. China

Abstract

A dinuclear Cu(II) complex [Cu2(L3)2]·2H2O, having an unprecedented in situ formed diphenolate 2,6-piperidin-4-one derived ligand produced from the flexible Schiff-base ligand HL1, can be yielded as a side product in the presence of Cu(OAc)2·H2O–NH3·H2O dissolved in methanol and acetone in addition to the expected dinuclear Cu(II) complex [Cu2(L1)4].

Graphical abstract: Dinuclear Cu(ii) complexes based on two flexible Schiff-base ligands and one unusual in situ formed diphenolate 2,6-piperidin-4-one derivative

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Article information

DOI
https://doi.org/10.1039/C4DT01014K
Article type
Communication
Submitted
05 Apr 2014
Accepted
24 Jul 2014
First published
24 Jul 2014

Dalton Trans., 2014,43, 13831-13834

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Dinuclear Cu(II) complexes based on two flexible Schiff-base ligands and one unusual in situ formed diphenolate 2,6-piperidin-4-one derivative

Y. Dai, Y. Wang, J. Geng, Y. Peng and W. Huang, Dalton Trans., 2014, 43, 13831 DOI: 10.1039/C4DT01014K

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