Cation-size-controlled assembly of the Ni(Ac)2–1,4-H2NDC system: geminal dicationic ionothermal syntheses, crystal structures and magnetic properties

Bing An; Yan Bai; Jun-Li Wang; Dong-Bin Dang

doi:10.1039/C4DT00987H

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Cation-size-controlled assembly of the Ni(Ac)₂–1,4-H₂NDC system: geminal dicationic ionothermal syntheses, crystal structures and magnetic properties†

Bing An,^a Yan Bai,*^ab Jun-Li Wang^a and Dong-Bin Dang*^a

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* Corresponding authors

^a Henan Key Laboratory of Polyoxometalate Chemistry. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P.R. China

^b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China
E-mail: baiyan@henu.edu.cn, dangdb@henu.edu.cn
Fax: (+86)-371-23881589
Tel: (+86)-371-23881589

Abstract

Geminal dicationic ionic liquids with different alkyl spacer lengths regularly tune four MOF structures of two structure types in the Ni(Ac)₂–1,4-H₂NDC system, which in turn bring about the magnetic properties divided into antiferromagnetic and ferromagnetic couplings consistent with the structures.

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Article information

DOI: https://doi.org/10.1039/C4DT00987H
Article type: Communication
Submitted: 03 Apr 2014
Accepted: 14 Jul 2014
First published: 14 Jul 2014

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Dalton Trans., 2014,43, 12828-12831

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Cation-size-controlled assembly of the Ni(Ac)₂–1,4-H₂NDC system: geminal dicationic ionothermal syntheses, crystal structures and magnetic properties

B. An, Y. Bai, J. Wang and D. Dang, Dalton Trans., 2014, 43, 12828 DOI: 10.1039/C4DT00987H

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