An unusual chiral 3D inorganic connectivity featuring a {Pb18} wheel: rapid and highly selective and sensitive sensing of Co(II)

Yun-Hu Han; Chong-Bin Tian; Shao-Wu Du

doi:10.1039/C4DT00905C

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An unusual chiral 3D inorganic connectivity featuring a {Pb₁₈} wheel: rapid and highly selective and sensitive sensing of Co(ii)†

Yun-Hu Han,^ab Chong-Bin Tian^ab and Shao-Wu Du*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: swdu@fjirsm.ac.cn
Fax: +86-591-83709470

^b Graduate University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

A pair of enantiomorphic frameworks featuring rare chiral 3D inorganic connectivity and a {Pb₁₈} wheel, has been obtained via spontaneous resolution. They exhibit rapid and highly selective and sensitive sensing of Co²⁺ ions.

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Article information

DOI: https://doi.org/10.1039/C4DT00905C
Article type: Communication
Submitted: 26 Mar 2014
Accepted: 22 Apr 2014
First published: 22 Apr 2014

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Dalton Trans., 2014,43, 11461-11464

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An unusual chiral 3D inorganic connectivity featuring a {Pb₁₈} wheel: rapid and highly selective and sensitive sensing of Co(II)

Y. Han, C. Tian and S. Du, Dalton Trans., 2014, 43, 11461 DOI: 10.1039/C4DT00905C

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Dalton Transactions