Doping cobalt into a [Zn7] cluster-based MOF to tune magnetic behaviour and induce fluorescence signal mutation

Yun-Wu Li; Sui-Jun Liu; Tong-Liang Hu; Xian-He Bu

doi:10.1039/C4DT00894D

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Doping cobalt into a [Zn₇] cluster-based MOF to tune magnetic behaviour and induce fluorescence signal mutation†

Yun-Wu Li,^ab Sui-Jun Liu,^a Tong-Liang Hu*^a and Xian-He Bu^a

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* Corresponding authors

^a Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry, and Synergetic Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China
E-mail: tlhu@nankai.edu.cn
Fax: +86-22-23502458

^b School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China

Abstract

An in situ doping strategy was successfully applied to tune the magnetic behaviour and induce fluorescence signal mutation of a spindle heptanuclear zinc cluster-based MOF, by only modifying its structural composition. The Co^II-doped Zn^II-MTV-M′MOF exhibits canted antiferromagnetism and weaker fluorescence properties.

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Article information

DOI: https://doi.org/10.1039/C4DT00894D
Article type: Communication
Submitted: 25 Mar 2014
Accepted: 28 Apr 2014
First published: 06 May 2014

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Dalton Trans., 2014,43, 11470-11473

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Doping cobalt into a [Zn₇] cluster-based MOF to tune magnetic behaviour and induce fluorescence signal mutation

Y. Li, S. Liu, T. Hu and X. Bu, Dalton Trans., 2014, 43, 11470 DOI: 10.1039/C4DT00894D

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