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Issue 28, 2014
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Uranyl-oxo coordination directed by non-covalent interactions

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Abstract

Directed coordination of weakly Lewis acidic K+ ions to weakly Lewis basic uranyl oxo ligands is accomplished through non-covalent cation–π and cation–F interactions for the first time. Comparison of a family of structurally related diarylamide ligands highlights the role that the cation–π and cation–F interactions play in guiding coordination. Cation binding to uranyl is demonstrated in the solid state and in solution, providing the shortest reported crystallographic uranyl-oxo to potassium distance. UV-Vis, TD-DFT calculations, and electrochemical measurements show that cation coordination directly impacts the electronics at the uranium(VI) cation.

Graphical abstract: Uranyl-oxo coordination directed by non-covalent interactions

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Publication details

The article was received on 13 Mar 2014, accepted on 15 May 2014 and first published on 16 May 2014


Article type: Paper
DOI: 10.1039/C4DT00763H
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2014,43, 10844-10851
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    Uranyl-oxo coordination directed by non-covalent interactions

    A. J. Lewis, H. Yin, P. J. Carroll and E. J. Schelter, Dalton Trans., 2014, 43, 10844
    DOI: 10.1039/C4DT00763H

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