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Issue 17, 2014
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A homoleptic η2 hydroxylaminato CeIV complex with S4 symmetry

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Abstract

An electron rich, air-stable hydroxylamine ligand and a strongly stabilized cerium(IV) hydroxylaminato complex are described. The synthesis of Ce[η2-ON(tBu)(2-OMe-5-tBu-C6H3)]4 (1) proceeded through a one pot protonolysis and oxidation procedure. Complex 1 crystallized with the molecule in exact S4 symmetry. The hydroxylaminato ligands were bound in an η2 mode that is of interest for potential application in the separations chemistry of rare earth metals.

Graphical abstract: A homoleptic η2 hydroxylaminato CeIV complex with S4 symmetry

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Publication details

The article was received on 26 Jan 2014, accepted on 24 Feb 2014 and first published on 26 Feb 2014


Article type: Communication
DOI: 10.1039/C4DT00287C
Citation: Dalton Trans., 2014,43, 6300-6303
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    A homoleptic η2 hydroxylaminato CeIV complex with S4 symmetry

    W. L. Dorfner, P. J. Carroll and E. J. Schelter, Dalton Trans., 2014, 43, 6300
    DOI: 10.1039/C4DT00287C

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