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Issue 7, 2014
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Structural and magnetic conformation of a cerocene [Ce(COT′′)2] exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

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Abstract

Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT′′) led to the formation of a staggered COT′′ arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.

Graphical abstract: Structural and magnetic conformation of a cerocene [Ce(COT′′)2]− exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

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Publication details

The article was received on 21 Nov 2013, accepted on 11 Dec 2013 and first published on 11 Dec 2013


Article type: Communication
DOI: 10.1039/C3DT53280A
Citation: Dalton Trans., 2014,43, 2737-2740
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    Structural and magnetic conformation of a cerocene [Ce(COT′′)2] exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

    J. J. Le Roy, I. Korobkov, J. E. Kim, E. J. Schelter and M. Murugesu, Dalton Trans., 2014, 43, 2737
    DOI: 10.1039/C3DT53280A

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