Issue 13, 2014
From the journal:

Dalton Transactions

Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center†

Zi-Jian Yao,a   Yue-Jian Lin,a   Bin Xua  and  Guo-Xin Jin*ab  

* Corresponding authors

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, P. R. China
E-mail: gxjin@fudan.edu.cn
Fax: (+86)-21-65641740

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, P. R. China

Abstract

Reaction of carboranyl anion or its thiolate derivative with a fully-substituted Cp*-based group 9 (Ir, Rh) metal complex affords respectively a C–C bond formation complex and a salt metathesis product. This example represents the first nucleophilic addition attempt in the area of M-Cp* chemistry.

Graphical abstract: Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center

  • This article is part of the themed collection: Carboranes
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Article information

DOI
https://doi.org/10.1039/C3DT51906F
Article type
Communication
Submitted
14 Jul 2013
Accepted
23 Jul 2013
First published
23 Jul 2013

Dalton Trans., 2014,43, 4938-4940

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Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center

Z. Yao, Y. Lin, B. Xu and G. Jin, Dalton Trans., 2014, 43, 4938 DOI: 10.1039/C3DT51906F

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