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Issue 14, 2016
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Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

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Abstract

This manuscript describes the systematic development of pyridine-type ligands, which promote the Pd catalyzed, non-directed amination of benzene in combination with novel, hydroxylamine-based electrophilic amination reagents. DFT calculations and mechanistic experiments provide insights into the factors influencing the arene C–H amination protocol.

Graphical abstract: Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

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Publication details

The article was received on 29 Feb 2016, accepted on 23 Mar 2016 and first published on 24 Mar 2016


Article type: Paper
DOI: 10.1039/C6CY00457A
Author version available: Download Author version (PDF)
Citation: Catal. Sci. Technol., 2016,6, 5304-5310
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    Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

    H. M. D. Bandara, D. Jin, M. A. Mantell, K. D. Field, A. Wang, R. P. Narayanan, N. A. Deskins and M. H. Emmert, Catal. Sci. Technol., 2016, 6, 5304
    DOI: 10.1039/C6CY00457A

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