Issue 7, 2014
From the journal:

Catalysis Science & Technology

Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources

Hallouma Bilel,ab   Naceur Hamdi,a   Fethi Zagrouba,a   Cédric Fischmeisterb  and  Christian Bruneau*b  

* Corresponding authors

a University of Carthage, Higher Institute of Sciences and Technology of Environment of Borj Cedria, B.P. 1003, Hammam-Lif, Tunisia
E-mail: naceur.hamdi@isste.rnu.tn

b UMR6226: CNRS-Université de Rennes1, Institut des Sciences Chimiques, Organometallics : Materials and Catalysis, Centre for Catalysis and Green Chemistry, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: christian.bruneau@univ-rennes1.fr

Abstract

We report a sequence of two ruthenium-catalyzed transformations, namely olefin cross-metathesis with allylic chlorides, followed by elimination, which gives a straightforward access to terminal 1,3-dienes from natural products.

Graphical abstract: Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources

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Article information

DOI
https://doi.org/10.1039/C4CY00315B
Article type
Paper
Submitted
12 Mar 2014
Accepted
04 Apr 2014
First published
07 Apr 2014

Catal. Sci. Technol., 2014,4, 2064-2071

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Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources

H. Bilel, N. Hamdi, F. Zagrouba, C. Fischmeister and C. Bruneau, Catal. Sci. Technol., 2014, 4, 2064 DOI: 10.1039/C4CY00315B

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