Jump to main content
Jump to site search

Issue 39, 2014
Previous Article Next Article

Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

Author affiliations

Abstract

Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

Graphical abstract: Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Aug 2014, accepted on 29 Aug 2014 and first published on 29 Aug 2014


Article type: Communication
DOI: 10.1039/C4CP03758H
Citation: Phys. Chem. Chem. Phys., 2014,16, 21230-21233
  •   Request permissions

    Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

    S. McMahon, J. Rochford, Y. Halpin, J. C. Manton, E. C. Harvey, G. M. Greetham, I. P. Clark, A. D. Rooney, C. Long and M. T. Pryce, Phys. Chem. Chem. Phys., 2014, 16, 21230
    DOI: 10.1039/C4CP03758H

Search articles by author

Spotlight

Advertisements