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Issue 16, 2014
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trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies

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Abstract

The auto-oxidation of trans-1,2-disiloxybenzocyclobutene 1 was found to be very efficient, giving endo-peroxide 7 in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2(3Σg) was studied by both EPR/spin trapping and theoretical studies.

Graphical abstract: trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies

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Publication details

The article was received on 02 Dec 2013, accepted on 13 Feb 2014 and first published on 17 Feb 2014


Article type: Paper
DOI: 10.1039/C3CP55077J
Citation: Phys. Chem. Chem. Phys., 2014,16, 7513-7520
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    trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies

    J. Drujon, R. Rahmani, V. Héran, R. Blanc, Y. Carissan, B. Tuccio, L. Commeiras and J. Parrain, Phys. Chem. Chem. Phys., 2014, 16, 7513
    DOI: 10.1039/C3CP55077J

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