Issue 13, 2014
From the journal:

Physical Chemistry Chemical Physics

Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

Guido Saracco,a   Svetoslava Vankova,a   Cristina Pagliano,a   Barbara Bonellia  and  Edoardo Garrone*a  

* Corresponding authors

a Department of Applied Science and Technology and INSTM Unit of Torino-Politecnico, Corso Duca degli Abruzzi, 24 Politecnico di Torino, I-10129 Turin, Italy
E-mail: edoardo.garrone@polito.it
Fax: +39-011-0904624

Abstract

Outer Co(II) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.

Graphical abstract: Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

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Article information

DOI
https://doi.org/10.1039/C3CP54896A
Article type
Paper
Submitted
20 Nov 2013
Accepted
13 Jan 2014
First published
13 Jan 2014

Phys. Chem. Chem. Phys., 2014,16, 6139-6145

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Outer Co(II) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water

G. Saracco, S. Vankova, C. Pagliano, B. Bonelli and E. Garrone, Phys. Chem. Chem. Phys., 2014, 16, 6139 DOI: 10.1039/C3CP54896A

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