Issue 35, 2014

Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

Abstract

Rigid tetrahedral ligands are of particular interest in Metal–Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting fluorite or garnet topology with copper(II), manganese(II) and cadmium(II) metal based nodes.

Graphical abstract: Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

Supplementary files

Article information

Article type
Communication
Submitted
08 Mar 2014
Accepted
09 Apr 2014
First published
22 Apr 2014

CrystEngComm, 2014,16, 8094-8097

Author version available

Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

I. Timokhin, A. J. P. White, P. D. Lickiss, C. Pettinari and R. P. Davies, CrystEngComm, 2014, 16, 8094 DOI: 10.1039/C4CE00486H

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