Issue 85, 2017
From the journal:

Chemical Communications

A cluster-based mesoporous Ti-MOF with sodalite supercages†

Chao Wang,‡ab   Chao Liu,‡ab   Xiang He*c  and  Zhong-Ming Sun ORCID logo *ad  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China
E-mail: szm@ciac.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, China

c Prof. X. He Department of Chemistry, Innovative Drug Research Center Shanghai University, Shanghai 200444, P. R. China
E-mail: hxiang@shu.edu.cn

d State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

Abstract

The cooperative assembly of a hexagonal column shaped [Ti6O6][iPrO]66+ cluster and rhomboid Cu2I2 dimers using isonicotinic acid results in an unprecedented three-dimensional (3D) highly crystalline cluster-based Ti-MOF that features both giant sodalite cages with an inner diameter of 2.8 × 3.2 nm2 and 3D open square channels.

Graphical abstract: A cluster-based mesoporous Ti-MOF with sodalite supercages

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Article information

DOI
https://doi.org/10.1039/C7CC06652J
Article type
Communication
Submitted
24 Aug 2017
Accepted
01 Oct 2017
First published
02 Oct 2017

Chem. Commun., 2017,53, 11670-11673

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A cluster-based mesoporous Ti-MOF with sodalite supercages

C. Wang, C. Liu, X. He and Z. Sun, Chem. Commun., 2017, 53, 11670 DOI: 10.1039/C7CC06652J

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