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Issue 28, 2016
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Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

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Abstract

We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction involves the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.

Graphical abstract: Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

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Publication details

The article was received on 20 Jan 2016, accepted on 10 Feb 2016 and first published on 12 Feb 2016


Article type: Communication
DOI: 10.1039/C6CC00556J
Citation: Chem. Commun., 2016,52, 4987-4990
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    Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

    A. F. Fearnley, J. An, M. Jackson, P. Lindovska and R. M. Denton, Chem. Commun., 2016, 52, 4987
    DOI: 10.1039/C6CC00556J

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