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Issue 73, 2015
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Identifying alkali metal inhibitors of crystal growth: a selection criterion based on ion pair hydration energy

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Abstract

We show that alkali metals function as effective modifiers of calcium oxalate monohydrate (COM) crystallization wherein alkali-oxalate ion parings reduce the rate of crystal growth by as much as 60%. Our findings reveal a distinct trend in alkali metal efficacy that cannot be explained by colloidal theories or simple descriptors, such as ion size, but is consistent with a theoretical model that accounts for the ion pair's affinity for water.

Graphical abstract: Identifying alkali metal inhibitors of crystal growth: a selection criterion based on ion pair hydration energy

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Publication details

The article was received on 27 May 2015, accepted on 29 Jul 2015 and first published on 29 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04361A
Citation: Chem. Commun., 2015,51, 13964-13967
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    Identifying alkali metal inhibitors of crystal growth: a selection criterion based on ion pair hydration energy

    S. Farmanesh, B. G. Alamani and J. D. Rimer, Chem. Commun., 2015, 51, 13964
    DOI: 10.1039/C5CC04361A

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