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Issue 11, 2015
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Organotemplate-free synthesis of an open-framework magnesium aluminophosphate with proton conduction properties

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Abstract

A new open-framework magnesium aluminophosphate MgAlP2O7(OH)(H2O)2 (denoted as JU102) has been hydrothermally synthesized by using an organotemplate-free synthetic route in the Al2O3–P2O5–MgO–H2O system. JU102 exhibits novel 4-connected zeolite-like topology with 8-ring channels. The existence of coordinated water and extensive H-bonds in the structure endows JU102 with unique proton conduction properties.

Graphical abstract: Organotemplate-free synthesis of an open-framework magnesium aluminophosphate with proton conduction properties

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Publication details

The article was received on 10 Nov 2014, accepted on 15 Dec 2014 and first published on 15 Dec 2014


Article type: Communication
DOI: 10.1039/C4CC08964B
Citation: Chem. Commun., 2015,51, 2149-2151
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    Organotemplate-free synthesis of an open-framework magnesium aluminophosphate with proton conduction properties

    Y. Mu, Y. Wang, Y. Li, J. Li and J. Yu, Chem. Commun., 2015, 51, 2149
    DOI: 10.1039/C4CC08964B

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