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Issue 25, 2015
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Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

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Abstract

The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite 1(FeSe2) tetrahedral chains separated by Fe–amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.

Graphical abstract: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

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Publication details

The article was received on 30 Oct 2014, accepted on 30 Nov 2014, published on 01 Dec 2014 and first published online on 01 Dec 2014


Article type: Communication
DOI: 10.1039/C4CC08608B
Citation: Chem. Commun., 2015,51, 5355-5358
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    Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

    J. T. Greenfield, C. Pak, S. Kamali, K. Lee and K. Kovnir, Chem. Commun., 2015, 51, 5355
    DOI: 10.1039/C4CC08608B

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