Issue 1, 2015
From the journal:

Chemical Communications

Fluoride, bifluoride and trifluoromethyl complexes of iridium(i) and rhodium(i)†

Byron J. Truscott,a   Fady Nahra,a   Alexandra M. Z. Slawin,a   David B. Cordesa  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM, School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife, UK
E-mail: snolan@st-andrews.ac.uk

Abstract

Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.

Graphical abstract: Fluoride, bifluoride and trifluoromethyl complexes of iridium(i) and rhodium(i)

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Article information

DOI
https://doi.org/10.1039/C4CC07772E
Article type
Communication
Submitted
01 Oct 2014
Accepted
27 Oct 2014
First published
27 Oct 2014

Chem. Commun., 2015,51, 62-65

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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

B. J. Truscott, F. Nahra, A. M. Z. Slawin, D. B. Cordes and S. P. Nolan, Chem. Commun., 2015, 51, 62 DOI: 10.1039/C4CC07772E

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