Issue 100, 2014

On-surface synthesis of organometallic complex via metal–alkene interactions

Abstract

From the interplay of high-resolution scanning tunneling microscopy (STM) imaging/manipulation and density functional theory (DFT) calculations, we have shown that the spontaneous formation of an organometallic complex by copper–alkene interactions can be successfully achieved, where the specific molecular adsorption geometry is revealed to be the key for facilitating such interaction.

Graphical abstract: On-surface synthesis of organometallic complex via metal–alkene interactions

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2014
Accepted
18 Sep 2014
First published
30 Sep 2014

Chem. Commun., 2014,50, 15924-15927

On-surface synthesis of organometallic complex via metal–alkene interactions

C. Zhang, Q. Sun, H. Kong, L. Wang, Q. Tan and W. Xu, Chem. Commun., 2014, 50, 15924 DOI: 10.1039/C4CC06925K

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