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Issue 82, 2014
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On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

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Abstract

We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

Graphical abstract: On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

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Publication details

The article was received on 04 Aug 2014, accepted on 26 Aug 2014 and first published on 27 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC06094F
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 12281-12284
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    On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

    M. B. Geeson, A. R. Jupp, J. E. McGrady and J. M. Goicoechea, Chem. Commun., 2014, 50, 12281
    DOI: 10.1039/C4CC06094F

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