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Issue 93, 2014
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Ultrafast energy transfer in a Pd(II)-bridged bisporphyrin dyad

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Abstract

A free base porphyrin/zinc(II)porphyrin dyad bridged by a Pd(II) unit exhibits an ultrafast S1 energy transfer (1.5 × 1012 s−1) due to significant MO couplings between the acceptor and the donor and a non-nil atomic contribution of the Pd-atom in the frontier MOs, hence ensuring π-conjugation.

Graphical abstract: Ultrafast energy transfer in a Pd(ii)-bridged bisporphyrin dyad

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Publication details

The article was received on 29 Jul 2014, accepted on 26 Sep 2014 and first published on 26 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05898D
Citation: Chem. Commun., 2014,50, 14609-14612
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    Ultrafast energy transfer in a Pd(II)-bridged bisporphyrin dyad

    M. Abdelhameed, A. Langlois, P. Karsenti, S. Richeter, R. Ruppert and P. D. Harvey, Chem. Commun., 2014, 50, 14609
    DOI: 10.1039/C4CC05898D

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