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Issue 84, 2014
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Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

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Abstract

The metalloligand [Ni(pedt)2] (pedt = 1-(pyridine-4-yl)ethylene-1,2-dithiolate) has been incorporated into two multi-dimensional structures for the first time. These coordination frameworks represent highly unusual interpenetration isomers and exhibit solid state redox and optical properties that reflect the electronically delocalised nature of the metalloligand.

Graphical abstract: Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

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Publication details

The article was received on 15 Jul 2014, accepted on 04 Sep 2014 and first published on 05 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05438E
Citation: Chem. Commun., 2014,50, 12772-12774
  • Open access: Creative Commons BY license
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    Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

    T. B. Faust, P. M. Usov, D. M. D'Alessandro and C. J. Kepert, Chem. Commun., 2014, 50, 12772
    DOI: 10.1039/C4CC05438E

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