Issue 74, 2014
From the journal:

Chemical Communications

Copper-promoted oxidative-fluorination of arylphosphine under mild conditions†

Na Liu,a   Liu-Liang Mao,a   Bin Yanga  and  Shang-Dong Yang*ab  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
E-mail: yangshd@lzu.edu.cn
Fax: +86-931-8912859
Tel: +86-931-8912859

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000, P. R. China

Abstract

An efficient method for the synthesis of phosphoric fluoride via oxidative coupling between hydrophosphine oxide and NaF is reported. DDQ serves as the oxidizing reagent as well as the hydrogen acceptor. The process involves a Cu(II) catalysis and exhibits great functional group tolerance under mild reaction conditions.

Graphical abstract: Copper-promoted oxidative-fluorination of arylphosphine under mild conditions

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Article information

DOI
https://doi.org/10.1039/C4CC04830J
Article type
Communication
Submitted
25 Jun 2014
Accepted
25 Jul 2014
First published
28 Jul 2014

Chem. Commun., 2014,50, 10879-10882

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Copper-promoted oxidative-fluorination of arylphosphine under mild conditions

N. Liu, L. Mao, B. Yang and S. Yang, Chem. Commun., 2014, 50, 10879 DOI: 10.1039/C4CC04830J

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