An octahedral bis-cyclometalated iridium(III) complex catalyzes the enantioselective α-amination of aldehydes with catalyst loadings down to 0.1 mol%. In this metal-templated design, the metal serves as a structural center and provides the exclusive source of chirality, whereas the catalysis is mediated through the organic ligand sphere.
H. Huo, C. Fu, C. Wang, K. Harms and E. Meggers, Chem. Commun., 2014, 50, 10409 DOI: 10.1039/C4CC04636F
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