Issue 81, 2014
From the journal:

Chemical Communications

Transfer hydrogenation of alkenes using Ni/Ru/Pt/Au heteroquatermetallic nanoparticle catalysts: sequential cooperation of multiple nano-metal species†

Yoshikazu Ito,a   Hidetoshi Ohta,b   Yoichi M. A. Yamada,b   Toshiaki Enokia  and  Yasuhiro Uozumi*abc  

* Corresponding authors

a Department of Chemistry, The Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Tokyo 152-8551, Japan

b RIKEN Center for Sustainable Resource Science, Hirosawa, Wako 351-0198, Japan

c Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan
E-mail: uo@ims.ac.jp
Fax: +81-564-59-5574

Abstract

Quatermetallic alloy nanoparticles of Ni/Ru/Pt/Au were prepared and found to promote the catalytic transfer hydrogenation of non-activated alkenes bearing conjugating units (e.g., 4-phenyl-1-butene) with 2-propanol, where the composition metals, Ni, Ru, Pt, and Au, act cooperatively to provide significant catalytic ability.

Graphical abstract: Transfer hydrogenation of alkenes using Ni/Ru/Pt/Au heteroquatermetallic nanoparticle catalysts: sequential cooperation of multiple nano-metal species

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Article information

DOI
https://doi.org/10.1039/C4CC04559A
Article type
Communication
Submitted
16 Jun 2014
Accepted
15 Aug 2014
First published
15 Aug 2014

Chem. Commun., 2014,50, 12123-12126

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Transfer hydrogenation of alkenes using Ni/Ru/Pt/Au heteroquatermetallic nanoparticle catalysts: sequential cooperation of multiple nano-metal species

Y. Ito, H. Ohta, Y. M. A. Yamada, T. Enoki and Y. Uozumi, Chem. Commun., 2014, 50, 12123 DOI: 10.1039/C4CC04559A

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