Issue 74, 2014

The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands

Abstract

A perfluorobutyl-functionalized two-dimensional porous coordination polymer (PCP), {[Cu(bpbtp)(L)(DMF)]·(DMF)}n (H2bpbtp = 2,5-bis(perfluorobutyl)terephthalic acid, L = 2,5-bis(perfluorobutyl)-1,4-bis(4-pyridyl)benzene, DMF = N,N-dimethylformamide) has been synthesized and structurally characterized. The pore surface of the PCP is decorated with pendant perfluorobutyl groups which fabricate a densely fluorinated nanospace resulting in unique gas sorption properties.

Graphical abstract: The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands

Supplementary files

Article information

Article type
Communication
Submitted
13 Jun 2014
Accepted
24 Jul 2014
First published
04 Aug 2014

Chem. Commun., 2014,50, 10861-10863

The densely fluorinated nanospace of a porous coordination polymer composed of perfluorobutyl-functionalized ligands

H. J. Jeon, R. Matsuda, P. Kanoo, H. Kajiro, L. Li, H. Sato, Y. Zheng and S. Kitagawa, Chem. Commun., 2014, 50, 10861 DOI: 10.1039/C4CC04505J

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