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Issue 92, 2014
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Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

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Abstract

Metal–ligand bifunctional cooperation has attracted much attention because it offers a powerful methodology to realize a number of highly efficient and selective catalysts. In this article, recent developments in the metal–ligand cooperative reactions of protic N-heterocyclic carbene (NHC) and pyrazole complexes bearing an acidic NH group at the position β to the metal are surveyed. Protic 2-pyridylidenes as related cooperating non-innocent ligands are also described.

Graphical abstract: Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

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Publication details

The article was received on 11 Jun 2014, accepted on 22 Jul 2014 and first published on 22 Jul 2014


Article type: Feature Article
DOI: 10.1039/C4CC04457F
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Citation: Chem. Commun., 2014,50, 14290-14300
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    Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

    S. Kuwata and T. Ikariya, Chem. Commun., 2014, 50, 14290
    DOI: 10.1039/C4CC04457F

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