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Issue 79, 2014
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Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

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Abstract

The forces required for the detachment of ferrocene (Fc) from β-cyclodextrin (βCD) in a single host (βCD)–guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex.

Graphical abstract: Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

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Publication details

The article was received on 28 May 2014, accepted on 07 Aug 2014 and first published on 08 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04102J
Citation: Chem. Commun., 2014,50, 11757-11759
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    Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

    V. Kolivoška, M. Mohos, I. V. Pobelov, S. Rohrbach, K. Yoshida, W. J. Hong, Y. C. Fu, P. Moreno-García, G. Mészáros, P. Broekmann, M. Hromadová, R. Sokolová, M. Valášek and Th. Wandlowski, Chem. Commun., 2014, 50, 11757
    DOI: 10.1039/C4CC04102J

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