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Issue 70, 2014
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Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

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Abstract

A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:] two-electron donor depending on the electronic state of the transition metal.

Graphical abstract: Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

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The article was received on 26 May 2014, accepted on 11 Jul 2014 and first published on 14 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04019H
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Citation: Chem. Commun., 2014,50, 10108-10111
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    Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

    I. L. Fedushkin, V. G. Sokolov, A. V. Piskunov, V. M. Makarov, E. V. Baranov and G. A. Abakumov, Chem. Commun., 2014, 50, 10108
    DOI: 10.1039/C4CC04019H

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