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Issue 82, 2014
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Probing the spatial and momentum distribution of confined surface states in a metal coordination network

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Abstract

The Shockley surface state on Cu(111) reacts sensitively to the perturbation by molecular adsorbates on the surface. In the porous structure of a metal-coordinated molecular network on Cu(111), the surface state is confined to a series of discrete states. Energy and momentum of eigenstates in the pores are related to both the energy dispersion of the free surface state and the geometric and energetic details of the confining barrier formed by the molecular network. The penetration of the confined state into the barrier is found to be sensitive to the constituting architectural elements.

Graphical abstract: Probing the spatial and momentum distribution of confined surface states in a metal coordination network

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Publication details

The article was received on 22 May 2014, accepted on 12 Aug 2014 and first published on 02 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC03941F
Citation: Chem. Commun., 2014,50, 12289-12292
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    Probing the spatial and momentum distribution of confined surface states in a metal coordination network

    J. Zhang, A. Shchyrba, S. Nowakowska, E. Meyer, T. A. Jung and M. Muntwiler, Chem. Commun., 2014, 50, 12289
    DOI: 10.1039/C4CC03941F

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