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Issue 67, 2014
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Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

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Abstract

The Pd/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.

Graphical abstract: Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

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Publication details

The article was received on 22 May 2014, accepted on 04 Jul 2014 and first published on 04 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03920C
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 9550-9553
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    Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

    B. Feng, H. Cheng, J. Chen, Q. Deng, L. Lu and W. Xiao, Chem. Commun., 2014, 50, 9550
    DOI: 10.1039/C4CC03920C

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