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Issue 63, 2014
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Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

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Abstract

The syntheses and X-ray crystal structures of dinuclear μ-azido and μ-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic structures and formal oxidation states of the metal centers are analyzed by theoretical and experimental methods, revealing the non-innocence of the PDI and nitrido ligands.

Graphical abstract: Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

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Publication details

The article was received on 14 May 2014, accepted on 06 Jun 2014 and first published on 09 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03624G
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Citation: Chem. Commun., 2014,50, 8735-8738
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    Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

    F. Angersbach-Bludau, C. Schulz, J. Schöffel and P. Burger, Chem. Commun., 2014, 50, 8735
    DOI: 10.1039/C4CC03624G

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