Issue 64, 2014

Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

Abstract

We have succeeded in the visible light-mediated synthetic use of α-aminoalkyl radicals derived from α-silyl secondary amines toward addition to α,β-unsaturated carbonyl compounds. The resulting γ-aminocarbonyl compounds are converted into γ-lactams and pyrroles in a one-pot process.

Graphical abstract: Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

Supplementary files

Article information

Article type
Communication
Submitted
23 Apr 2014
Accepted
12 Jun 2014
First published
16 Jun 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 8900-8903

Author version available

Synthesis of nitrogen heterocycles via α-aminoalkyl radicals generated from α-silyl secondary amines under visible light irradiation

K. Nakajima, M. Kitagawa, Y. Ashida, Y. Miyake and Y. Nishibayashi, Chem. Commun., 2014, 50, 8900 DOI: 10.1039/C4CC03000A

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