Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface

Cici Wang; Qitang Fan; Shanwei Hu; Huanxin Ju; Xuefei Feng; Yong Han; Haibin Pan; Junfa Zhu; J. Michael Gottfried

doi:10.1039/C4CC02919D

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Coordination reaction between tetraphenylporphyrin and nickel on a TiO₂(110) surface†

Cici Wang,^a Qitang Fan,^a Shanwei Hu,^a Huanxin Ju,^a Xuefei Feng,^a Yong Han,^a Haibin Pan,^a Junfa Zhu*^a and J. Michael Gottfried*^b

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* Corresponding authors

^a National Synchrotron Radiation Laboratory and Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, P. R. China
E-mail: jfzhu@ustc.edu.cn

^b Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-St., 35032 Marburg, Germany
E-mail: michael.gottfried@chemie.uni-marburg.de

Abstract

In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO₂(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.

This article is part of the themed collection: Scanning Probe Studies of Molecular Systems

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Article information

DOI: https://doi.org/10.1039/C4CC02919D
Article type: Communication
Submitted: 19 Apr 2014
Accepted: 20 May 2014
First published: 20 May 2014

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Chem. Commun., 2014,50, 8291-8294

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Coordination reaction between tetraphenylporphyrin and nickel on a TiO₂(110) surface

C. Wang, Q. Fan, S. Hu, H. Ju, X. Feng, Y. Han, H. Pan, J. Zhu and J. M. Gottfried, Chem. Commun., 2014, 50, 8291 DOI: 10.1039/C4CC02919D

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