Jump to main content
Jump to site search

Issue 57, 2014
Previous Article Next Article

Covalent assembly of a two-dimensional molecular “sponge” on a Cu(111) surface: confined electronic surface states in open and closed pores

Author affiliations

Abstract

We present a new class of on-surface covalent reactions, formed between diborylene-3,4,9,10-tetraaminoperylene and trimesic acid on Cu(111), which gives rise to a porous 2D-‘sponge’. This aperiodic network allowed the investigation of the dependence of electron confinement effects upon pore size, shape and even in partial confinement.

Graphical abstract: Covalent assembly of a two-dimensional molecular “sponge” on a Cu(111) surface: confined electronic surface states in open and closed pores

Back to tab navigation

Supplementary files

Publication details

The article was received on 03 Apr 2014, accepted on 18 May 2014 and first published on 04 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC02463J
Citation: Chem. Commun., 2014,50, 7628-7631
  • Open access: Creative Commons BY license
  •   Request permissions

    Covalent assembly of a two-dimensional molecular “sponge” on a Cu(111) surface: confined electronic surface states in open and closed pores

    A. Shchyrba, S. C. Martens, C. Wäckerlin, M. Matena, T. Ivas, H. Wadepohl, M. Stöhr, T. A. Jung and L. H. Gade, Chem. Commun., 2014, 50, 7628
    DOI: 10.1039/C4CC02463J

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements